Preparation of organolanthanide halides by oxidative addition of RHal to metallic lanthanides

The possibility is demonstrated of obtaining organometallic compounds of trivalent lanthanides through oxidative addition of triphenylmethyl chloride, benzyl chloride and phenyl bromide to metallic lanthanides (Pr, Nd, Gd, Ho) in THF. The composition and stability of the organometallic compounds as...

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Bibliographic Details
Published inJournal of organometallic chemistry Vol. 255; no. 1; pp. 71 - 79
Main Authors Dolgoplosk, B.A., Tinyakova, E.I., Markevich, I.N., Soboleva, T.V., Chernenko, G.M., Sharev, O.K., Yakovlev, V.A.
Format Journal Article
LanguageEnglish
Published Lausanne Elsevier B.V 01.01.1983
Elsevier Science
Subjects
Chemistry
Exact sciences and technology
Miscellaneous
Organic chemistry
Organometalloidal and organometallic compounds
Preparations and properties
Lanthanide Organic compounds
Addition reaction
Oxidation
Neodymium Organic compounds
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Summary:The possibility is demonstrated of obtaining organometallic compounds of trivalent lanthanides through oxidative addition of triphenylmethyl chloride, benzyl chloride and phenyl bromide to metallic lanthanides (Pr, Nd, Gd, Ho) in THF. The composition and stability of the organometallic compounds as functions of the reaction conditions and metal nature have been studied. The reaction mechanism is discussed.
ISSN:0022-328X
1872-8561
DOI:10.1016/0022-328X(83)80174-0