Nanostructure morphology and atomically resolved images of chains and planes of YBCO single crystals grown with different additives

• Published in: Journal of crystal growth Vol. 158; no. 3; pp. 248 - 254
• Main Authors: Narlikar, A.V., Samanta, S.B., Changkang, Chen, Yongle, Hu, Hodby, J.W., Wanklyn, B.M.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 1996; Elsevier
• Subjects: Condensed matter: electronic structure, electrical, magnetic, and optical properties; Cross-disciplinary physics: materials science; rheology; Cuprates superconductors (high tc and insulating parent compounds); Exact sciences and technology; Growth from solutions; High-Tc compounds; Materials science; Methods of crystal growth; physics of crystal growth; Physics; Superconductivity; Y-based cuprates; Additives; Transition temperature; Inorganic compounds; Flux growth; Transition element compounds; Bismuth oxides; Experimental study; Order disorder; STM; Contamination; Surface structure; Monocrystals; Barium fluorides; Barium oxides; High-Tc superconductors; Crystal growth from solutions; Boron oxides; Quaternary compounds; Copper oxides; Yttrium oxides; Electric conductivity
• ISSN: 0022-0248; 1873-5002
• DOI: 10.1016/0022-0248(96)80030-3

Bulk single crystals of superconducting YBCO (YBa 2Cu 3O 7), grown with incorporation of different additives like BaF 2, B 2O 3 and Bi 2O 3, have been investigated to gain an insight into the problem of combating T c degradation due to aluminium contamination from the crucible material. Electron probe microanalysis (EPMA) along with T c values of the above crystals, shows that, with BaF 2 introduced as additive, the contamination due to aluminium is significantly reduced, which improves crystal growth and superconductivity. The crystals have been subjected to high resolution imaging of planes and chains using STM, while the ensuing changes in the conductance spectra of chains due to Al contamination were studied by scanning tunnelling spectroscopy (STS). The contamination of CuO chains is corroborated by chains becoming quasi-insulating on account of substitutional disorder, and also by the increase in their surface roughness at the atomic level. The effect of additives is discussed and the observed T c variation is linked with the relative changes in the adulteration and disordering of CuO chains. The results are in general accord with the role of interlayer coupling between CuO 2 planes and other effects that are known to control the T c of layered cuprates.