Electrochromic devices based on thin metallopolymeric films

Recent work from our own lab on electrochromic thin-film metallopolymers is surveyed and summarized. The survey includes discussion of (1) new electrochemical synthetic methods based on reductive halide loss or oxidative activation for nucleophilic attack, (2) spatially selective, multicomponent fil...

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Bibliographic Details
Published inSolar energy materials and solar cells Vol. 25; no. 3; pp. 315 - 325
Main Authors Zhang, Hai-Tao, Subramanian, P., Fussa-Rydel, Odette, Bebel, James C., Hupp, Joseph T.
Format Journal Article Conference Proceeding
LanguageEnglish
Published Amsterdam Elsevier B.V 01.02.1992
Elsevier
Subjects
Application fields
Applied sciences
Exact sciences and technology
Polymer industry, paints, wood
Technology of polymers
Composite film
Nitrogen heterocycle polymer
Electrochemical device
Optical recording
Organometallic polymer
Preparation
Use
Rhenium Complexes
Ruthenium III Complexes
Electrochemical polymerization
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Summary:Recent work from our own lab on electrochromic thin-film metallopolymers is surveyed and summarized. The survey includes discussion of (1) new electrochemical synthetic methods based on reductive halide loss or oxidative activation for nucleophilic attack, (2) spatially selective, multicomponent film formation based on semiconductor bandgap illumination, followed by electropolymerization, (3) spatially selective film formation based on solution-phase (monomer) photoredox chemistry, and (4) reversible electrochromic image recording, based on a combination of semiconductor electrode illumination and polymer-phase metal-metal bond chemistry.
ISSN:0927-0248
1879-3398
DOI:10.1016/0927-0248(92)90076-2