Measurement of activity of gallium in GaSbIn alloys by emf method using zirconia as solid electrolyte

EMF of galvanic cells with zirconia solid electrolytes was measured to determine the activity of gallium in liquid GaSbIn alloys in the temperature range 1050–1150 K in the entire composition range. Fe, Fe x O mixtures were used as a reference electrode. Isoactivity curves in the ternary GaSbIn...

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Published inJournal of non-crystalline solids Vol. 156; pp. 393 - 397
Main Authors Katayama, Iwao, Nakayama, Jun-ichiro, Ikura, Tsuneo, Tanaka, Toshihiro, Kozuka, Zensaku, Iida, Takamichi
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.05.1993
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Summary:EMF of galvanic cells with zirconia solid electrolytes was measured to determine the activity of gallium in liquid GaSbIn alloys in the temperature range 1050–1150 K in the entire composition range. Fe, Fe x O mixtures were used as a reference electrode. Isoactivity curves in the ternary GaSbIn alloy were derived by combining the activity data of GaSb and GaIn alloys, and the shape of the curves exhibits a slight bend from the GaSb side to the GaIn side. The results were compared with literature data.
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ISSN:0022-3093
1873-4812
DOI:10.1016/0022-3093(93)90204-B