Rhodium Carbonyl Catalyzed Carbonylation of Unsaturated Compounds. IV. Carbonylation and Oligomerization of Diphenylacetylene Catalyzed by Co4(CO)12, Rh4(CO)12, and Ir4(CO)12 under Pressure of Carbon Monoxide
In the presence of Co4(CO)12, Rh4(CO)12, and Ir4(CO)12 catalysts the reaction of diphenylacetylene (1) in 2-propanol under pressure of carbon monoxide gave the hydrocarbonylation products 2 and/or 3 and the oligomers 4 and/or 5, in which the ratios depended on the catalyst employed.
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| Published in | Bulletin of the Chemical Society of Japan Vol. 63; no. 1; pp. 247 - 248 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Tokyo
The Chemical Society of Japan
01.01.1990
Chemical Society of Japan |
| Online Access | Get full text |
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| Summary: | In the presence of Co4(CO)12, Rh4(CO)12, and Ir4(CO)12 catalysts the reaction of diphenylacetylene (1) in 2-propanol under pressure of carbon monoxide gave the hydrocarbonylation products 2 and/or 3 and the oligomers 4 and/or 5, in which the ratios depended on the catalyst employed. |
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| ISSN: | 0009-2673 1348-0634 |
| DOI: | 10.1246/bcsj.63.247 |