Metal–metal bond energy in a binuclear molybdenum(III) aqua complex

The enthalpies of oxidation of mononuclear [Mo(H 2O) 6] 3+ and binuclear [Mo 2(μ-OH) 2(H 2O) 8] 4+ complexes in aqueous solutions were determined by calorimetric titration, and the metal–metal bond energy was estimated.

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Bibliographic Details
Published inMendeleev communications Vol. 13; no. 6; pp. 252 - 253
Main Authors Proyavkin, Alexander A., Dementiev, Ilia A., Kozin, Andrei O., Kondratiev, Yuri V., Korolkov, Dimitry V.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 2003
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Summary:The enthalpies of oxidation of mononuclear [Mo(H 2O) 6] 3+ and binuclear [Mo 2(μ-OH) 2(H 2O) 8] 4+ complexes in aqueous solutions were determined by calorimetric titration, and the metal–metal bond energy was estimated.
ISSN:0959-9436
1364-557X
DOI:10.1070/MC2003v013n06ABEH001732