Efficient blue organic light-emitting devices with a new bipolar emitter

• Published in: Organic electronics Vol. 12; no. 2; pp. 358 - 363
• Main Authors: Tao, Silu, Jiang, Yilan, Lai, Shiu-Lun, Fung, Man-Keung, Zhou, Yechun, Zhang, Xiaohong, Zhao, Weiming, Lee, Chun-Sing
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 01.02.2011; Elsevier
• Subjects: Applied sciences; Bipolar emitter; Blue emitter; Electronics; Exact sciences and technology; OLED; Optoelectronic devices; Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices; Bipolar emitter; OLED; Blue emitter; Performance evaluation; Multifunctionality; Transport properties; Lithium fluoride; Luminescence; Transmitter; Doped materials; Multiple layer; Charge transport; Indium oxide; Glass transition temperature; Thermal stability; Tin addition; Light emitting device; Polycyclic aromatic amines; Optoelectronic device; Organic light emitting diodes; Blue light; Organic electronics
• ISSN: 1566-1199; 1878-5530
• DOI: 10.1016/j.orgel.2010.12.001

The molecular structure of the bipolar emitter; I-V-L characteristics of the device based on the bipolar emitter, inset: current and power efficiencies of the device. [Display omitted] ► New multifunctional 4,4′-di-(1-pyrenyl)-4′′-[2-(9,9′-dimethylfluorene)]-triphenylamine (DPFA) has been designed, synthesized, and applied as host emitter, electron- and hole-transporters in organic light-emitting devices (OLEDs). ► DPFA exhibits good thermal stability with a glass transition temperature ( T g) of 161 °C and shows blue emissions in both solution and films. ► DPFA has efficient bipolar charge transport properties for both hole and electron. ► Highly efficient blue emission with a maximum luminescence efficiency of 5.1 cd/A (5.3 lm/W) is obtained in DPFA based devices. A new multifunctional compound, 4,4′-di-(1-pyrenyl)-4′′-[2-(9,9′-dimethylfluorene)]-triphenylamine (DPFA) has been designed, synthesized and applied respectively as host-emitter, electron- and hole-transporters in organic light-emitting devices (OLEDs). The compound exhibits good thermal stability with a glass transition temperature ( T g) of 161 °C and shows blue emissions in both solution and films. OLEDs with DPFA playing various roles have been fabricated and characterized. The results show that DPFA has efficient bipolar charge transport properties for both hole and electron. By using DPFA as a blue emitter in a typical three layer device with a configuration of ITO/NPB(50 nm)/DPFA(20 nm)/TPBI(30 nm)/LiF(0.5 nm)/MgAg, highly efficient blue emission with a maximum luminescence efficiency of 5.1 cd/A (5.3 lm/W) is obtained.