Aqueous solution-chemical derived Ni–Al2O3 solar selective absorbing coatings

• Published in: Solar energy materials and solar cells Vol. 105; pp. 90 - 95
• Main Authors: Li, Zhenxiang, Zhao, Jianxi, Ren, Lihui
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 01.10.2012; Elsevier
• Subjects: Absorptance; Absorption; Absorptivity; Aluminum; Applied sciences; Aqueous solution-chemical preparation; Coatings; Emittance; Energy; Exact sciences and technology; Nanostructure; Natural energy; Nickel; Ni–Al2O3 absorbing coating; Solar collectors; Solar energy; Solar thermal conversion; Aqueous solution-chemical preparation; Ni–Al2O3 absorbing coating; Wetting; Nanoparticle; In situ; Chemical method; Nickel nitrate; Aluminium; Absorption coefficient; High temperature; absorbing coating; Solar absorbers; O; Optical properties; Chemical preparation; Ni―Al; Selective coating; Chelating agent; Nickel; Aqueous solution; Alumina; Protective coatings; Double layers; Cost lowering
• ISSN: 0927-0248; 1879-3398
• DOI: 10.1016/j.solmat.2012.05.030

Here we report the preparation of Ni–Al2O3 absorbing coatings by a facile aqueous solution-chemical method. In this approach, aluminum nitrate and nickel nitrate were simply mixed in water as precursor solution together with a chelating agent and a wetting agent, all of which were of low cost and available commercially. At high temperature and in N2 atmosphere, aluminum ions were converted into an Al2O3 matrix and nickel ions were in situ reduced into nano-size nickel particles embedded in the Al2O3 matrix. The optimum single layer attained a high normal solar absorptance of 0.85 and a low normal thermal emittance of 0.03. A three-layer coating, i.e. double absorption layers together with one top anti-reflection layer, exhibited better optical properties of absorptance/thermal emittance=0.93/0.05, respectively, and was stable in air up to 300°C. The Ni–Al2O3 absorbing coating prepared by aqueous solution-chemistry method has excellent optical properties and high thermal stability. [Display omitted] ► Ni–Al2O3 cermet solar coatings were fabricated by an aqueous solution-chemistry method. ► Precursor solutions were prepared by mixing nitrates, chelating agent and wetting agent. ► Nickel ions were in situ reduced into nano-size nickel particles. ► Optimum single layer attained a high normal solar absorptance of 0.85. ► Three-layer coating achieved an absorptance of 0.93 and was stable in air up to 300°C.