Novel palladium-catalyzed diarylation and dialkenylation reactions of norbornene derivatives

Norbornene and its derivatives are diarylated or dialkenylated by aryl- or alkenyltributylstannanes, a palladium catalyst, and chloroacetone or chloroacetonitrile as a reoxidant.

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Bibliographic Details
Published inSynlett no. 5; pp. 477 - 479
Main Authors Fugami, K, Hagiwara, S, Oda, H, Kosugi, M
Format Journal Article
LanguageEnglish
Published STUTTGART Thieme Medical Publishers 01.05.1998
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
TERNARY COUPLING REACTION
IODOTRIMETHYLSILANE
chloroacetone
difunctionalization
palladium(II) catalyst
alkenyltin
ALKYNES
ALKYNYLTINS
STEREOSELECTIVE SYNTHESIS
ORGANOTIN COMPOUNDS
NORBORNADIENE
PHENYLTRIBUTYLTIN
aryltin
STEREODEFINED ENYNES
ORGANIC HALIDES
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Summary:Norbornene and its derivatives are diarylated or dialkenylated by aryl- or alkenyltributylstannanes, a palladium catalyst, and chloroacetone or chloroacetonitrile as a reoxidant.
ISSN:0936-5214
DOI:10.1055/s-1998-1710