Magnetic and specific heat studies of the frustrated Er2Mn2O7 compound
A new ErzMn207 compound was synthesized by the ceramic method and its crystal structure was characterized LJsing powder X-ray diffraction (XRD) and observed by scanning electron microscopy (SEM). The magnetic properties were investigated using a BS2 magnetometer and the heat capacity was studied usi...
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Published in | Journal of rare earths Vol. 31; no. 1; pp. 54 - 59 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
Elsevier B.V
2013
Elsevier |
Subjects | |
Online Access | Get full text |
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Summary: | A new ErzMn207 compound was synthesized by the ceramic method and its crystal structure was characterized LJsing powder X-ray diffraction (XRD) and observed by scanning electron microscopy (SEM). The magnetic properties were investigated using a BS2 magnetometer and the heat capacity was studied using a quantum design (PPMS). The structural study revealed that this compound was monophasic and crystallized in the monoclinic system with the P2/M space group. Magnetization measurements were carried out in the temperature range of 1.8-200 K under an applied magnetic field of 0.05 T. A crossover from a room temperature para- magnetic phase to an antiferromagnetic one at low temperature was detected from the magnetic study. The magnetic susceptibility, in the paramagnetic region above 40 K, was found to present a simple Curie-Weiss type behavior. From the specific heat (G,) measurements in magnetic fields up to 5 T, we noted the presence of a wide peak characteristic of a second order magneto-structural transition. |
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Bibliography: | magnetic frustration; magnetic phase transition; specific heat; rare earths A new ErzMn207 compound was synthesized by the ceramic method and its crystal structure was characterized LJsing powder X-ray diffraction (XRD) and observed by scanning electron microscopy (SEM). The magnetic properties were investigated using a BS2 magnetometer and the heat capacity was studied using a quantum design (PPMS). The structural study revealed that this compound was monophasic and crystallized in the monoclinic system with the P2/M space group. Magnetization measurements were carried out in the temperature range of 1.8-200 K under an applied magnetic field of 0.05 T. A crossover from a room temperature para- magnetic phase to an antiferromagnetic one at low temperature was detected from the magnetic study. The magnetic susceptibility, in the paramagnetic region above 40 K, was found to present a simple Curie-Weiss type behavior. From the specific heat (G,) measurements in magnetic fields up to 5 T, we noted the presence of a wide peak characteristic of a second order magneto-structural transition. 11-2788/TF ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23 |
ISSN: | 1002-0721 2509-4963 |
DOI: | 10.1016/S1002-0721(12)60234-8 |