A stereocontrolled route to cyclohexylethanoid natural products

Rengyol and seven related cyclohexylethanoid natural products have been synthesized in a stereocontrolled manner from a common starting material. In the present study the absolute configuration of the three chiral products has been determined and the first synthesis of a cyclohexylethanoid natural p...

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Bibliographic Details
Published inSynlett no. 9; pp. 1001 - 1004
Main Authors Honzumi, M, Kamikubo, T, Ogasawara, K
Format Journal Article
LanguageEnglish
Published STUTTGART Thieme Medical Publishers 01.09.1998
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
RENGYOL
natural products
MITSUNOBU REACTION
configuration
FORSYTHIA-SUSPENSA
stereocontrol
resolution
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Summary:Rengyol and seven related cyclohexylethanoid natural products have been synthesized in a stereocontrolled manner from a common starting material. In the present study the absolute configuration of the three chiral products has been determined and the first synthesis of a cyclohexylethanoid natural product bearing an oxetane ring has been accomplished.
ISSN:0936-5214
DOI:10.1055/s-1998-1851