Transient ion pairs from OH-radical reactions: Pulse radiolysis of aqueous alkyl iodide solutions

Pulse radiolysis studies of aqueous alkyl iodide solutions reveal the existence of the transient ion pair (HOI−.R+)aq. This species is formed by OH-radical reaction with the alkyl iodide followed by a rapid solvent-assisted rearrangement from the outer to the inner charge-transfer complex.

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Bibliographic Details
Published inChemical physics letters Vol. 21; no. 2; pp. 412 - 414
Main Authors Brühlmann, U., Büchler, H., Marchetti, F., Bühler, R.E.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 15.08.1973
Elsevier
Subjects
AQUEOUS SOLUTIONS
HYDROXYL RADICALS- CHEMICAL REACTIONS
IODINATED ALIPHATIC HYDROCARBONS- RADIOLYSIS
ION PAIRS
N40300 -Chemistry-Radiation Chemistry
ORGANIC IODINE COMPOUNDS- RADIOLYSIS
PULSED IRRADIATION
RADIATION CHEMISTRY
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Summary:Pulse radiolysis studies of aqueous alkyl iodide solutions reveal the existence of the transient ion pair (HOI−.R+)aq. This species is formed by OH-radical reaction with the alkyl iodide followed by a rapid solvent-assisted rearrangement from the outer to the inner charge-transfer complex.
Bibliography:USDOE
ISSN:0009-2614
1873-4448
DOI:10.1016/0009-2614(73)80169-1