Photodissociation of Nitrous Oxide by Slice Ion Imaging: The Stagnation Pressure Dependence
Photodissociation of nitrous oxide near 203 nm has been studied by a combination of high resolution slice ion imaging technique and (2+1) resonance-enhanced multiphoton ionization (REMPI) spectroscopy of N2(X1Σg +) via the (a″1Σg +) state. We have measured the recoil velocity and angular distributio...
Saved in:
Published in | Bulletin of the Korean Chemical Society Vol. 30; no. 11; pp. 2661 - 2664 |
---|---|
Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
Published |
대한화학회
20.11.2009
|
Subjects | |
Online Access | Get full text |
Cover
Loading…
Summary: | Photodissociation of nitrous oxide near 203 nm has been studied by a combination of high resolution slice ion imaging technique and (2+1) resonance-enhanced multiphoton ionization (REMPI) spectroscopy of N2(X1Σg +) via the (a″1Σg +) state. We have measured the recoil velocity and angular distributions of N2 fragments by ion images of the state-resolved photofragments. The N2 fragments were highly rotationally excited and the NN-O bond dissociation energy was determined to be 3.635 eV. Also, we investigated the photofragment images from the photodissociation of N2O clusters with various stagnation pressures. KCI Citation Count: 2 |
---|---|
Bibliography: | G704-000067.2009.30.11.025 |
ISSN: | 0253-2964 1229-5949 |
DOI: | 10.5012/bkcs.2009.30.11.2661 |