Direct synthesis of nitriles by Cu/DMEDA/TEMPO-catalyzed aerobic oxidation of primary amines with air

By screening the copper catalysts,ligands,and the reaction conditions,a simple CuCl/DMEDA/TEMPO catalyst system readily available from commercial sources is developed for a direct and selective synthesis of the useful nitriles by an aerobic oxidation reaction of primary amines using air as an advant...

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Bibliographic Details
Published inChinese chemical letters Vol. 28; no. 6; pp. 1336 - 1339
Main Authors Ma, Xian-Tao, Xu, Hao, Xiao, Ying-Lin, Su, Chen-Liang, Liu, Jian-Ping, Xu, Qing
Format Journal Article
LanguageEnglish
Published NEW YORK Elsevier B.V 01.06.2017
Elsevier
Subjects
Aerobic oxidation
Air
Amines
Chemistry
Chemistry, Multidisciplinary
Copper catalysis
Nitriles
Physical Sciences
Science & Technology
Nitriles
Amines
Air
Copper catalysis
Aerobic oxidation
ROOM-TEMPERATURE
CONVERSION
IMINES
HYDRATION
ALCOHOLS
EFFICIENT CATALYST
DEHYDROGENATION
ARYL HALIDES
METAL
AMIDES
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Summary:By screening the copper catalysts,ligands,and the reaction conditions,a simple CuCl/DMEDA/TEMPO catalyst system readily available from commercial sources is developed for a direct and selective synthesis of the useful nitriles by an aerobic oxidation reaction of primary amines using air as an advantageous oxidant under mild conditions.
Bibliography:Aerobic oxidation Air Amines Copper catalysis Nitriles
11-2710/O6
By screening the copper catalysts,ligands,and the reaction conditions,a simple CuCl/DMEDA/TEMPO catalyst system readily available from commercial sources is developed for a direct and selective synthesis of the useful nitriles by an aerobic oxidation reaction of primary amines using air as an advantageous oxidant under mild conditions.
ISSN:1001-8417
1878-5964
DOI:10.1016/j.cclet.2017.01.017