Synthesis of (Sn,Zn)(O,S) bimetallic oxysulfide catalyst for the detoxification of Cr+6 in aqueous solution
The reduction reaction mechanism for Cr(VI) under visible light by Sn-20 catalyst. [Display omitted] •The new designed (Sn,Zn)(O,S) bimetallic oxysulfide catalyst was synthesized.•The synthesis was a single-step, easy, and done at low temperature below 100 °C.•The effect of the amount of Zn to (Sn,...
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Published in | Advanced powder technology : the international journal of the Society of Powder Technology, Japan Vol. 30; no. 12; pp. 3099 - 3106 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
Elsevier B.V
01.12.2019
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Subjects | |
Online Access | Get full text |
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Summary: | The reduction reaction mechanism for Cr(VI) under visible light by Sn-20 catalyst.
[Display omitted]
•The new designed (Sn,Zn)(O,S) bimetallic oxysulfide catalyst was synthesized.•The synthesis was a single-step, easy, and done at low temperature below 100 °C.•The effect of the amount of Zn to (Sn, Zn) (O, S) were studied systematically.•The (Sn,Zn)(O,S) oxiysulfide had excellent performance for reduction of Cr+6.
Herein, we report the bimetallic (Sn,Zn)(O,S) oxysulfide nanocatalyst with a facile method. The Sn-based catalyst with the addition of Zn was synthesized with the proportions of 0, 20, 30 and 50% of Zn to Sn precursors for preparation. The catalysts were characterized by XRD, TEM, SEM XPS, and UV–vis instruments. The nanocatalysts were also tested for the detoxification of Cr+6. The Sn-20 catalyst with 20 M percent of Zn(Ac)2·2H2O showed an excellent performance for the induced photocatalytic reduction of Cr+6 under visible light irradiation at room temperature. The complete reduction of Cr+6 was achieved within 80 min by Sn-20 catalyst. However, 85.6, 97, and 94% of Cr+6 reductions were achieved within 80 min under visible light illumination by Sn-0, Sn-30, and Sn-50 catalysts, respectively. Hence, the bimetallic (Sn,Zn)(O,S) oxysulfide nanocatalyst will be a candidate and highly potential material for the detoxification of Cr(VI)-containing polluted water. |
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ISSN: | 0921-8831 1568-5527 |
DOI: | 10.1016/j.apt.2019.09.016 |