Synthesis of 5-vinyl-2-norbornene through Diels-Alder reaction of cyclopentadiene with 1,3-butadiene in supercritical carbon dioxide

An efficient method for the synthesis of 5-vinyl-2-norbornene from cyclopentadiene and 1,3-butadiene was developed.The Diels-Alder reaction of cyclopentadiene with 1,3-butadiene proceeded smoothly in supercritical carbon dioxide in the absence of any polymerization inhibitor to produce the correspon...

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Bibliographic Details
Published inChinese chemical letters Vol. 28; no. 4; pp. 900 - 904
Main Authors Meng, Fan-Qiang, Feng, Xiu-Juan, Wang, Wan-Hui, Bao, Ming
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.04.2017
Subjects
1,3-Butadiene
5-Vinyl-2-norbornene
Cyclopentadiene
Diels-Alder reaction
Supercritical carbon dioxide
Supercritical carbon dioxide
Diels-Alder reaction
Cyclopentadiene
1,3-Butadiene
5-Vinyl-2-norbornene
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Summary:An efficient method for the synthesis of 5-vinyl-2-norbornene from cyclopentadiene and 1,3-butadiene was developed.The Diels-Alder reaction of cyclopentadiene with 1,3-butadiene proceeded smoothly in supercritical carbon dioxide in the absence of any polymerization inhibitor to produce the corresponding5-vinyl-2-norbornene in satisfactory yield with high selectivity.
Bibliography:11-2710/O6
5-Vinyl-2-norbornene Diels-Alder reaction Cyclopentadiene 1,3-Butadiene Supercritical carbon dioxide
An efficient method for the synthesis of 5-vinyl-2-norbornene from cyclopentadiene and 1,3-butadiene was developed.The Diels-Alder reaction of cyclopentadiene with 1,3-butadiene proceeded smoothly in supercritical carbon dioxide in the absence of any polymerization inhibitor to produce the corresponding5-vinyl-2-norbornene in satisfactory yield with high selectivity.
ISSN:1001-8417
1878-5964
DOI:10.1016/j.cclet.2016.12.018