Chalcopyrite Leaching Kinetics in the Presence of Methanol

• Published in: International journal of chemical reactor engineering Vol. 17; no. 12
• Main Authors: Solís Marcial, O. J., Nájera Bastida, A., Bañuelos, J. E., Valdés Martínez, O. U., Luevano, L. A., Serrano Rosales, B.
• Format: Journal Article
• Language: English
• Published: De Gruyter 01.12.2019
• Subjects: chalcopyrite; hydrogen peroxide; leaching; methanol; shrinking core model
• ISSN: 1542-6580; 1542-6580
• DOI: 10.1515/ijcre-2019-0081

The dissolution of chalcopyrite under near ambient conditions represents one of the main challenges in the copper industry. Thus, various routes have been proposed for chalcopyrite treatment, such as the use of polar organic solvents, and this has shown promising results. In this paper, we present a study of copper leaching from a chalcopyrite concentrate in aqueous acidic medium with methanol and various H concentrations at 15, 30, and 40 °C. The results show that nearly complete copper extraction was attained within 5 h at 40 °C. The extraction percentages were plotted as functions of time at each temperature. The experimental data were modeled using the shrinking core model considering the cylindrical particle shape (shrinking cylinder model) within acceptable confidence levels, yielding an estimated activation energy of 24.3 kJ/mol. Furthermore, the process was dependent on the H concentration, and it acts as a reagent rather than an oxidant in the leaching reaction. It was found that sulfur is the only species present in the solid phase formed during the leaching of chalcopyrite, demonstrating the co-dissolution of both copper and iron.