New symmetrically substituted 1,3,5-triazines as host compounds for channel-type inclusion formation

A new synthetic procedure for the production of symmetrically substituted 1,3,5-triazines by cyclization from aromatic nitriles in the molten state with zinc chloride as a catalyst has been developed and applied for a number of aromatic and fluoro aromatic nitriles. The new triazine 8 [2,4,6-tris(4&...

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Published inCrystEngComm Vol. 14; no. 3; pp. 768 - 770
Main Authors Berger, Ricarda, Hauser, Jürg, Labat, Gaël, Weber, Edwin, Hulliger, Jürg
Format Journal Article
LanguageEnglish
Published 01.01.2012
Subjects
Aromatic compounds
Catalysts
Channels
Crystals
Inclusions
Nitriles
Solvents
Zinc chlorides
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Summary:A new synthetic procedure for the production of symmetrically substituted 1,3,5-triazines by cyclization from aromatic nitriles in the molten state with zinc chloride as a catalyst has been developed and applied for a number of aromatic and fluoro aromatic nitriles. The new triazine 8 [2,4,6-tris(4'-bromobiphenylyl)-1,3,5-triazine] is shown to form channel-type inclusion compounds with several aromatic solvents, featuring two different channels in the same crystal.
Bibliography:ObjectType-Article-2
SourceType-Scholarly Journals-1
ObjectType-Feature-1
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ISSN:1466-8033
1466-8033
DOI:10.1039/C2CE06034E