Solvent and additive-free selective aerobic allylic hydroxylation of β-pinene catalyzed by metalloporphyrins

• Published in: Chinese chemical letters Vol. 28; no. 3; pp. 575 - 578
• Main Authors: Xu, Shi-Chao, Zhu, Shou-Ji, Bi, Liang-Wu, Chen, Yu-Xiang, Wang, Jing, Lu, Yan-Ju, Gu, Yan, Zhao, Zhen-Dong
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.03.2017
• Subjects: Aerobic allylic hydroxylation; Biomimetic catalysis; Metalloporphyrin; Turpentine transformation; β-Pinene; Metalloporphyrin; Turpentine transformation; β-Pinene; Aerobic allylic hydroxylation; Biomimetic catalysis

Metallodeuteroporphyrins（MDPs） were employed as the catalysts for aerobic oxidation of β-pinene in absence of solvents and additives. Allylic hydroxylation products were found to be the main products from this protocol. The catalytic activity of MDPs with different metal nuclei and the influences of...