Solvent and additive-free selective aerobic allylic hydroxylation of β-pinene catalyzed by metalloporphyrins

Metallodeuteroporphyrins（MDPs） were employed as the catalysts for aerobic oxidation of β-pinene in absence of solvents and additives. Allylic hydroxylation products were found to be the main products from this protocol. The catalytic activity of MDPs with different metal nuclei and the influences of...

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Bibliographic Details
Published inChinese chemical letters Vol. 28; no. 3; pp. 575 - 578
Main Authors Xu, Shi-Chao, Zhu, Shou-Ji, Bi, Liang-Wu, Chen, Yu-Xiang, Wang, Jing, Lu, Yan-Ju, Gu, Yan, Zhao, Zhen-Dong
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.03.2017
Subjects
Aerobic allylic hydroxylation
Biomimetic catalysis
Metalloporphyrin
Turpentine transformation
β-Pinene
Metalloporphyrin
Turpentine transformation
β-Pinene
Aerobic allylic hydroxylation
Biomimetic catalysis
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Summary:Metallodeuteroporphyrins（MDPs） were employed as the catalysts for aerobic oxidation of β-pinene in absence of solvents and additives. Allylic hydroxylation products were found to be the main products from this protocol. The catalytic activity of MDPs with different metal nuclei and the influences of technological conditions on this reaction were investigated. This catalytic system has bright application prospect since only eco-friendly and readily available dioxygen were needed.
Bibliography:11-2710/O6
Turpentine transformatio β-Pinene Metalloporphyrin Biomimetic catalysis Aerobic allylic hydroxylation
Metallodeuteroporphyrins（MDPs） were employed as the catalysts for aerobic oxidation of β-pinene in absence of solvents and additives. Allylic hydroxylation products were found to be the main products from this protocol. The catalytic activity of MDPs with different metal nuclei and the influences of technological conditions on this reaction were investigated. This catalytic system has bright application prospect since only eco-friendly and readily available dioxygen were needed.
ISSN:1001-8417
1878-5964
DOI:10.1016/j.cclet.2016.11.020