Solvent and additive-free selective aerobic allylic hydroxylation of β-pinene catalyzed by metalloporphyrins
Metallodeuteroporphyrins（MDPs） were employed as the catalysts for aerobic oxidation of β-pinene in absence of solvents and additives. Allylic hydroxylation products were found to be the main products from this protocol. The catalytic activity of MDPs with different metal nuclei and the influences of...
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| Published in | Chinese chemical letters Vol. 28; no. 3; pp. 575 - 578 |
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| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
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Elsevier B.V
01.03.2017
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| Abstract | Metallodeuteroporphyrins（MDPs） were employed as the catalysts for aerobic oxidation of β-pinene in absence of solvents and additives. Allylic hydroxylation products were found to be the main products from this protocol. The catalytic activity of MDPs with different metal nuclei and the influences of technological conditions on this reaction were investigated. This catalytic system has bright application prospect since only eco-friendly and readily available dioxygen were needed. |
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| AbstractList | Metallodeuteroporphyrins（MDPs） were employed as the catalysts for aerobic oxidation of β-pinene in absence of solvents and additives. Allylic hydroxylation products were found to be the main products from this protocol. The catalytic activity of MDPs with different metal nuclei and the influences of technological conditions on this reaction were investigated. This catalytic system has bright application prospect since only eco-friendly and readily available dioxygen were needed. [Display omitted] An efficient MPs catalyzed aerobic oxidation method of β-pinene was established. Allylic hydroxylation products could be obtained in high selectivity. Metallodeuteroporphyrins (MDPs) were employed as the catalysts for aerobic oxidation of β-pinene in absence of solvents and additives. Allylic hydroxylation products were found to be the main products from this protocol. The catalytic activity of MDPs with different metal nuclei and the influences of technological conditions on this reaction were investigated. This catalytic system has bright application prospect since only eco-friendly and readily available dioxygen were needed. |
| Author | Shi-Chao Xu Shou-Ji Zhu Liang-Wu Bi Yu-Xiang Chen Jing Wang Yan-Ju Lu Yan Gu Zhen-Dong Zhao |
| AuthorAffiliation | Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, Nanjing 210042, China Key Lab. of Biomass Energy and Material, Jiangsu Province, Nanjing 210042, China National Engineering Lab. for Biomass Chemical Utilization, Nanjing 210042, China Key and Open Lab. on Forest Chemical Engineering, State Forestry Administration, Nanjing 210042, China Institute of Forestry New Technology, Chinese Academy of Forestry, Beijing, 100091, China 2011 Collaborative Innovation Center of Jiangxi Typical Trees Cultivation and Utilization in Jiangni Agricultural University, Nanchang, 330045, China |
| Author_xml | – sequence: 1 givenname: Shi-Chao surname: Xu fullname: Xu, Shi-Chao organization: Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, Nanjing 210042, China – sequence: 2 givenname: Shou-Ji surname: Zhu fullname: Zhu, Shou-Ji organization: Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, Nanjing 210042, China – sequence: 3 givenname: Liang-Wu surname: Bi fullname: Bi, Liang-Wu organization: Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, Nanjing 210042, China – sequence: 4 givenname: Yu-Xiang surname: Chen fullname: Chen, Yu-Xiang organization: Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, Nanjing 210042, China – sequence: 5 givenname: Jing surname: Wang fullname: Wang, Jing organization: Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, Nanjing 210042, China – sequence: 6 givenname: Yan-Ju surname: Lu fullname: Lu, Yan-Ju organization: Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, Nanjing 210042, China – sequence: 7 givenname: Yan surname: Gu fullname: Gu, Yan organization: Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, Nanjing 210042, China – sequence: 8 givenname: Zhen-Dong surname: Zhao fullname: Zhao, Zhen-Dong email: zdzhao@189.cn organization: Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, Nanjing 210042, China |
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| Keywords | Metalloporphyrin Turpentine transformation β-Pinene Aerobic allylic hydroxylation Biomimetic catalysis |
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| Notes | 11-2710/O6 Turpentine transformatio β-Pinene Metalloporphyrin Biomimetic catalysis Aerobic allylic hydroxylation Metallodeuteroporphyrins（MDPs） were employed as the catalysts for aerobic oxidation of β-pinene in absence of solvents and additives. Allylic hydroxylation products were found to be the main products from this protocol. The catalytic activity of MDPs with different metal nuclei and the influences of technological conditions on this reaction were investigated. This catalytic system has bright application prospect since only eco-friendly and readily available dioxygen were needed. |
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| Snippet | Metallodeuteroporphyrins（MDPs） were employed as the catalysts for aerobic oxidation of β-pinene in absence of solvents and additives. Allylic hydroxylation... [Display omitted] An efficient MPs catalyzed aerobic oxidation method of β-pinene was established. Allylic hydroxylation products could be obtained in high... |
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| SubjectTerms | Aerobic allylic hydroxylation Biomimetic catalysis Metalloporphyrin Turpentine transformation β-Pinene |
| Title | Solvent and additive-free selective aerobic allylic hydroxylation of β-pinene catalyzed by metalloporphyrins |
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