Controlled synthesis of a functionalized polytungstate ligand and a {M a M b M c (PW 9 ) 2 } sandwich complex

The synthesis of an unprecedented vacant polytungstate ligand and its use to obtain a crystallographically characterized {MaMbMc(PW9)2}-type sandwich structure, the first example of the purposeful and controlled metal incorporation into a derivatized POM, are reported.

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Bibliographic Details
Published inCrystEngComm Vol. 13; no. 3; pp. 738 - 740
Main Authors Cao, Rui, O'Halloran, Kevin P., Hillesheim, Daniel A., Lense, Sheri, Hardcastle, Kenneth I., Hill, Craig L.
Format Journal Article
LanguageEnglish
Published 01.01.2011
Subjects
Acetal resins
Crystallography
Ligands
Sandwich structures
Synthesis
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Summary:The synthesis of an unprecedented vacant polytungstate ligand and its use to obtain a crystallographically characterized {MaMbMc(PW9)2}-type sandwich structure, the first example of the purposeful and controlled metal incorporation into a derivatized POM, are reported.
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ISSN:1466-8033
1466-8033
DOI:10.1039/C0CE00828A