Highly efficient single-layer organic light-emitting devices based on a bipolar pyrazine/carbazole hybrid host material
Organic light-emitting diodes (OLEDs) have attracted tremendous interest and have already become a prevalent technology in MP3 players, smartphones and cameras. In response to the calls for the large-scale application of OLEDs, the complicated and costly processes for preparing a device is a major c...
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Published in | Journal of materials chemistry. C, Materials for optical and electronic devices Vol. 2; no. 14; pp. 2488 - 2495 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
Published |
01.01.2014
|
Subjects | |
Online Access | Get full text |
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Summary: | Organic light-emitting diodes (OLEDs) have attracted tremendous interest and have already become a prevalent technology in MP3 players, smartphones and cameras. In response to the calls for the large-scale application of OLEDs, the complicated and costly processes for preparing a device is a major challenge which should be addressed. Herein, a novel bipolar host material,
26PyzCz
, which contains a pyrazine/carbazole hybrid, has been designed and synthesized.
26PyzCz
-based single-layer (SL) fluorescent (F)–phosphorescent (P) OLEDs with various colors have been successfully fabricated. Green and orange SL phosphorescent OLEDs (PHOLEDs) have exhibited efficiencies as high as 63.3 and 62.1 cd A
−1
at 1000 cd m
−2
, and 55.7 and 53.8 cd A
−1
at 10 000 cd m
−2
, respectively. Meanwhile, a SL warm white OLED based on fluorescent blue and phosphorescent orange has demonstrated excellent performance, with a maximum current efficiency of 27.5 cd A
−1
and a maximum power efficiency of 21.6 lm W
−1
. In addition, the charge carrier behavior have been evaluated by impedance spectroscopy, which revealed that the dopant trapping effect plays a critical role in charge balance and exciton generation in the SL PHOLEDs. |
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Bibliography: | ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23 |
ISSN: | 2050-7526 2050-7534 |
DOI: | 10.1039/C3TC32301C |