Rh(III)-catalyzed aldehyde C–H bond functionalization of salicylaldehydes with arylboronic acids

A Rh(III)-catalyzed aldehyde C–H bond functionalization of salicylaldehydes with arylboronic acids has been developed, with features of mild reaction condition and high efficiency. Furthermore, the functionalized 2-hydroxybenzophenone could be subject to divergent synthesis of heterocycles. [Display...

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Bibliographic Details
Published inTetrahedron Vol. 71; no. 45; pp. 8511 - 8516
Main Authors Wang, Dahai, Cui, Sunliang
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 11.11.2015
Elsevier
Subjects
2-Hydroxybenzophenones
acids
aldehydes
catalysts
chemical bonding
chemical reactions
chemical structure
Chemistry
Chemistry, Organic
C–H activation
Divergent synthesis
Physical Sciences
Rh(III) catalysis
rhodium
Salicylaldehydes
Science & Technology
Salicylaldehydes
C–H activation
Divergent synthesis
2-Hydroxybenzophenones
Rh(III) catalysis
ACTIVATION
ALKYNES
CLEAVAGE
REARRANGEMENT
C-H activation
FACILE SYNTHESIS
BENZAMIDES
SELECTIVE INHIBITORS
DERIVATIVES
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Summary:A Rh(III)-catalyzed aldehyde C–H bond functionalization of salicylaldehydes with arylboronic acids has been developed, with features of mild reaction condition and high efficiency. Furthermore, the functionalized 2-hydroxybenzophenone could be subject to divergent synthesis of heterocycles. [Display omitted]
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2015.09.053