In situ synthesis of silver nanoparticles on densely amine‐functionalized polystyrene: Highly active nanocomposite catalyst for the reduction of methylene blue

• Published in: Polymers for advanced technologies Vol. 30; no. 2; pp. 320 - 328
• Main Authors: Amari, Heni, Guerrouache, Mohamed, Mahouche‐Chergui, Samia, Abderrahim, Raoudha, Carbonnier, Benjamin
• Format: Journal Article
• Language: English
• Published: Bognor Regis Wiley Subscription Services, Inc 01.02.2019
• Subjects: Borohydrides; Catalysis; Catalytic activity; Chelation; Chemical synthesis; dye reduction; functional polystyrene; Infrared analysis; Methylene blue; nanocomposite catalyst; Nanocomposites; Nanoparticles; Nitration; Organic chemistry; Polystyrene resins; polystyrene‐gold composite; Reduction; Scanning electron microscopy; Silver; Spectrophotometry; Sulfuric acid; Thermogravimetric analysis; X-ray diffraction
• ISSN: 1042-7147; 1099-1581
• DOI: 10.1002/pat.4468

In this contribution, polystyrene (PS) bearing nitrogen‐rich ligands as chelation moieties for both Ag+ ions and Ag(0) nanoparticles was prepared through successive chemical modifications of native PS including nitration (treatment with HNO3/H2SO4), reductive amination (treatment with SnCl2/HCl), Michael addition of methyl acrylate, and grafting of ethyelenediamine. The as‐synthesized PS derivative was further used to support silver nanoparticles through initial chelation of the silver nanoparticle ions precursor and subsequent chemical in situ reduction with sodium borohydride. Chemical structure of the PS derivatives was confirmed after each synthesis step by using complementary characterization methods including infrared and energy‐dispersive X‐ray spectroscopies, elemental analysis, X‐ray diffraction, thermogravimetric analysis, and scanning electron microscopy. The catalytic activity of the PS‐EAD/AgNP nanocomposite was demonstrated using the reduction of methylene blue to leucomethylene blue, as a model reaction. The reaction was monitored by UV‐vis spectrophotometry and achieved with an excess of sodium borohydride allowing for a pseudo‐first‐order analysis of the kinetic reaction parameters. Quantitative reduction of the methylene blue was obtained upon successive catalytic cycles with a rate constant value of 0.4016 minute−1.