Synthesis, Structure and Characterization of a Novel Two-Dimensional Supramolecular Mn(II) Coordination Polymer Constructed from a 1,10-Phenanthroline Derivative and a Flexible Dicarboxylate

The title complex, [Mn (glu)(L) (HL) ]・0.5H O (H glu = glutaric acid, HL = 2-(2-chloro-6-fluorophenyl)-1Himidazo[ 4,5-f][1,10]phenanthroline) has been synthesized using a hydrothermal method and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. Crystal data:...

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Published inZeitschrift für Naturforschung. B, A journal of chemical sciences Vol. 65; no. 9; pp. 1173 - 1176
Main Authors Kong, Zhi-Guo, Ma, Xiao-Yuan, Xu, Zhan-Lin
Format Journal Article
LanguageEnglish
Published Verlag der Zeitschrift für Naturforschung 01.09.2010
Subjects
1,10-Phenanthroline Derivative
Coordination Polymer
Crystal Structure
Glutaric Acid
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Summary:The title complex, [Mn (glu)(L) (HL) ]・0.5H O (H glu = glutaric acid, HL = 2-(2-chloro-6-fluorophenyl)-1Himidazo[ 4,5-f][1,10]phenanthroline) has been synthesized using a hydrothermal method and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. Crystal data: C Cl Mn , triclinic, space group P1¯, a = 14.932(5), b = 16.414(5), c = 17.891(5) Å , α = 115.851(5), β = 91.288(5), γ = 112.894(5)◦, V = 3536.4(19) Å , Z = 1. Compound 1 exhibits 1D chains which are further stacked by C-H...π interactions to give two-dimensional supramolecular layers.
ISSN:0932-0776
1865-7117
DOI:10.1515/znb-2010-0920