THE NORPHTHALOCYANINES BEARING TWO TTF UNITS: SYNTHESIS, PHOTOPHYSICAL AND ELECTROCHEMICAL PROPERTIES

A magnesium norphthalocyanine (6a) was prepared by the mixed condensation of phthalonitrile in excess with the dithiomaleonitrile bearing two TTF units (5), using Mg(11) as a template. Subsequent demetalation of 6a with acetic acid gave 6b in good yield. The structures of target compounds were deter...

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Bibliographic Details
Published inHeterocycles Vol. 83; no. 8; pp. 1859 - 1866
Main Authors Hou, Ruibin, Jiang, Cuiping, Chen, Tie, Jin, Long-Yi, Yin, Bingzhu
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier 2011
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
METALLOPHTHALOCYANINES
Tetrathiafulvalene
MACROCYCLES
Dithiomaleionitrile
COMPLEXES
SUBSTITUENTS
Phthalonitrile
Metal-Free Norphthalocyanine
Magnesium Norphthalocyanine
CHEMISTRY
PHTHALOCYANINES
TRIAZOLEPHTHALOCYANINES
SOLITAIRE-PORPHYRAZINES
AGGREGATION
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Summary:A magnesium norphthalocyanine (6a) was prepared by the mixed condensation of phthalonitrile in excess with the dithiomaleonitrile bearing two TTF units (5), using Mg(11) as a template. Subsequent demetalation of 6a with acetic acid gave 6b in good yield. The structures of target compounds were determined by EA, NMR and TOF MS and their electrochemical and optical properties were also studied by cyclic voltammetry and UV-vis spectroscopy.
ISSN:0385-5414
DOI:10.3987/COM-11-12235