Separation of Rh(III) from the Mixed Chloride Solutions Containing Pt(IV) and Pd(II) by Extraction with Alamine336

• Published in: Bulletin of the Korean Chemical Society Vol. 31; no. 7; pp. 1945 - 1950
• Main Authors: Sun, Panpan, Lee, Myung-Ho, Lee, Man-Seung
• Format: Journal Article
• Language: English
• Published: 대한화학회 20.07.2010
• Subjects: 화학
• ISSN: 0253-2964; 1229-5949
• DOI: 10.5012/bkcs.2010.31.7.1945

Solvent extraction experiments of Pt(IV), Pd(II) and Rh(III) by Alamine336 were performed from the mixed chloride solutions. In the HCl concentration range from 1 to 5 M, most of Pt and Pd were extracted from the mixed solutions. However,the extraction percentage of Rh was much smaller than that of Pt and Pd. Lower concentration of Alamine336 in strong HCl solution led to higher separation factor of Rh from Pt and Pd. Adding SnCl2 to the mixed solutions increased the extraction percentage of Rh, while the extraction percentage of Pt and Pd was little affected. Our results showed that selective separation of Rh or coextraction of the three platinum group metals from the mixed solution would be possible by adjusting the extraction conditions. KCI Citation Count: 11