Novel and Chemoselective Dehydrogenation of 3,4-Dihydropyrimidin-2(1H)-ones with 1,4-Bis(triphenylphosphonium)-2-butene Peroxodisulfate

3,4-Dihydropyrimidin-2(1H)-ones were efficiently converted into the corresponding pyrimidin-2(1H)-ones in high yields within a short period of time on treatment with aqueous acetonitrile using 1,4-bis(triphenyl phosphonium)-2-butene peroxodisulfate. Chemoselective oxidation of 3,4-dihydropyrimidin i...

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Bibliographic Details
Published inBulletin of the Korean Chemical Society Vol. 34; no. 6; pp. 1751 - 1754
Main Author Gorjizadeh, Maryam
Format Journal Article
LanguageEnglish
Published WEINHEIM Wiley 20.06.2013
대한화학회
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
화학
OXIDATION
BIGINELLI-TYPE
PEROXYDISULFATE
1,4-Bis(triphenylphosphonium)-2-butene peroxodisulfate
Dehydrogenation
ONE-POT SYNTHESIS
3,4-Dihydropyrimidin-2(1H)-ones
Pyrimidin-2(1H)-ones
PROTOCOL
EFFICIENT REAGENT
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Summary:3,4-Dihydropyrimidin-2(1H)-ones were efficiently converted into the corresponding pyrimidin-2(1H)-ones in high yields within a short period of time on treatment with aqueous acetonitrile using 1,4-bis(triphenyl phosphonium)-2-butene peroxodisulfate. Chemoselective oxidation of 3,4-dihydropyrimidin in the presence of other oxidizable functional groups was also achieved by this reagent.
Bibliography:G704-000067.2013.34.6.048
http://journal.kcsnet.or.kr/main/j_search/j_abstract_view.htm?code=B130626&qpage=j_search&spage=b_bkcs&dpage=ar
ISSN:1229-5949
0253-2964
1229-5949
DOI:10.5012/bkcs.2013.34.6.1751