Oligomerization of higher α-olefins over catalysts containing an F-4SF perfluorinated copolymer

The oligomerization of higher α-olefins over a set of heterogeneous mesoporous catalysts has been studied using the example of decene-1. It has been shown that mesoporous catalysts based on the sulfonated, perfluorinated copolymer F-4SF exhibit high activity in oligomerization of decene-1 in both a...

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Published inPetroleum chemistry Vol. 54; no. 2; pp. 120 - 127
Main Authors Maksimov, A. L., Kulikov, A. B., Pugacheva, A. A., Vilesov, A. S., Smirnov, M. B., Galkina, E. V., Reshetnikov, D. M., Zvinchuk, A. A.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.03.2014
Springer
Subjects
Catalysts
Chemistry
Chemistry and Materials Science
Fighter planes
Industrial Chemistry/Chemical Engineering
Olefins
Oligomers
perfluorinated copolymer
decene-1
oligomerization
mesoporous catalysts
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Summary:The oligomerization of higher α-olefins over a set of heterogeneous mesoporous catalysts has been studied using the example of decene-1. It has been shown that mesoporous catalysts based on the sulfonated, perfluorinated copolymer F-4SF exhibit high activity in oligomerization of decene-1 in both a batch reactor and a flow system: in the former case, the olefin conversion reaches 95–99% with the yield of dimers of 90–95%; in the latter case, the conversion of decene-1 to oligomers exceeds 70%.
ISSN:0965-5441
1555-6239
DOI:10.1134/S0965544114020066