Induced long-range order in crosslinked 'one-dimensional' stacks of fluid monolayers

• Published in: Nature (London) Vol. 389; no. 6651; pp. 576 - 579
• Main Authors: de Jeu, Wim H, Wong, Gerald C. L, Shao, Henry, Liang, Keng S, Zentel, Rudolf
• Format: Journal Article
• Language: English
• Published: London Nature Publishing 09.10.1997; Nature Publishing Group
• Subjects: Condensed matter: structure, mechanical and thermal properties; Engineering; Exact sciences and technology; Experimental determinations of smectic, nematic, cholesteric, and other structures; Liquid crystals; Nanotechnology; Physics; Scientific imaging; Structure of solids and liquids; crystallography; X-ray diffraction; Smectic crystals; Cross-linking; Long-range order; XRD; Experimental study; Liquid crystals; One-dimensional systems
• ISSN: 0028-0836; 1476-4687
• DOI: 10.1038/39271

Ordinary crystals are characterized by long-range translational order in all three dimensions. In lower-dimensional systems, in contrast, translational order is destroyed through the 'Landau-Peierls instability' - displacements from periodic ordering due to thermal fluctuations whose amplitude increases with the size of the system. This effect is well known for layered systems ordered in one dimension, such as surfactant membranes,, smectic (layered) liquid crystals and liquid crystalline polymers, which form ordered stacks of fluid monolayers. Smectic liquid-crystal polymers can be weakly crosslinked to form percolating elastomeric networks that still allow mobility on a molecular scale,. In these smectic elastomers, fluctuations of the fluid layers are coupled to distortions of the underlying network, and are therefore energetically penalized, even though the network of crosslinks has a random nature and thus no three-dimensional translational order. Here we present a high-resolution X-ray diffraction study of a smectic elastomer that reveals the effects of crosslinking on long-range ordering. We find that the introduction of a random network of crosslinks enhances the stability of the layered structure against thermal fluctuations and suppresses the Landau-Peierls instability so as to induce 'one-dimensional' long-range ordering at length-scales up to several micrometres.