Rhodium(III)-catalyzed annulative coupling between arenes and sulfoxonium ylides via C-H activation

The Rh(iii)-catalyzed annulative C-H functionalization of arenes with sulfoxonium ylides has been realized. Arenes assisted by diverse nucleophilic directing groups are viable substrates, and the coupling affords structurally diverse fused hetero- and carbocycles under redox-neutral conditions.

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Bibliographic Details
Published inORGANIC CHEMISTRY FRONTIERS Vol. 5; no. 6; pp. 998 - 1002
Main Authors Zheng, Guangfan, Tian, Miaomiao, Xu, Youwei, Chen, Xiaohong, Li, Xingwei
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2018
Royal Society of Chemistry
Subjects
Aromatic compounds
Chemistry
Chemistry, Organic
Coupling
Organic chemistry
Physical Sciences
Rhodium
Science & Technology
Substrates
SULFOXIMINES
BETA-PHENYLETHYLAMINES
ISOQUINOLINE ALKALOIDS
N BOND FORMATION
OXIDATIVE ANNULATION
ALKYNES
ALPHA-DIAZO ESTERS
CARBENOID FUNCTIONALIZATION
RHODIUM CATALYSIS
GENERAL-METHOD
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Summary:The Rh(iii)-catalyzed annulative C-H functionalization of arenes with sulfoxonium ylides has been realized. Arenes assisted by diverse nucleophilic directing groups are viable substrates, and the coupling affords structurally diverse fused hetero- and carbocycles under redox-neutral conditions.
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ISSN:2052-4129
2052-4110
2052-4110
DOI:10.1039/c7qo01033h