A Convenient Preparation of Arylthioynamines

(2,2,2-Trifluoroethylthio)benzenes prepared from sodium thiolates and 2,2,2-trifluoroethyl p-toluenesulfonate reacted with 3 equiv of lithium dialkylamides in diethyl ether to give arylthioynamines in good yields. The present procedure gives good results with aliphatic sulflde.

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Bibliographic Details
Published inBulletin of the Chemical Society of Japan Vol. 50; no. 11; pp. 3069 - 3070
Main Authors Nakai, Takeshi, Tanaka, Kiyoshi, Setoi, Hiroyuki, Ishikawa, Nobuo
Format Journal Article
LanguageEnglish
Published The Chemical Society of Japan 01.11.1977
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Summary:(2,2,2-Trifluoroethylthio)benzenes prepared from sodium thiolates and 2,2,2-trifluoroethyl p-toluenesulfonate reacted with 3 equiv of lithium dialkylamides in diethyl ether to give arylthioynamines in good yields. The present procedure gives good results with aliphatic sulflde.
ISSN:0009-2673
1348-0634
DOI:10.1246/bcsj.50.3069