Reduction of Ketones and Aldehydes via Catalytic Hydrosilylation Using Triethoxysilane and Trimethoxysilane

It was found that ketones and aldehydes can be effectively reduced via catalytic hydrosilylation using triethoxysilane and trimethoxysilane in the presence of RhCl(PPh3)3 or RuCl2(PPh3)3, followed by ethanolysis or methanolysis.

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Bibliographic Details
Published in	Bulletin of the Chemical Society of Japan Vol. 54; no. 4; pp. 1279 - 1280
Main Authors	Matsumoto, Hideyuki, Hoshino, Yoshikazu, Nagai, Yoichiro
Format	Journal Article
Language	English
Published	The Chemical Society of Japan 01.04.1981
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Summary:	It was found that ketones and aldehydes can be effectively reduced via catalytic hydrosilylation using triethoxysilane and trimethoxysilane in the presence of RhCl(PPh3)3 or RuCl2(PPh3)3, followed by ethanolysis or methanolysis.
ISSN:	0009-2673 1348-0634
DOI:	10.1246/bcsj.54.1279