A strategy for effective electrochemical detection of hydroquinone and catechol: Decoration of alkalization-intercalated Ti3C2 with MOF-derived N-doped porous carbon

• Published in: Sensors and actuators. B, Chemical Vol. 320; p. 128386
• Main Authors: Huang, Runmin, Liao, Dan, Chen, Sisi, Yu, Jingang, Jiang, Xinyu
• Format: Journal Article
• Language: English
• Published: Lausanne Elsevier B.V 01.10.2020; Elsevier Science Ltd
• Subjects: Alkalizing; Benzoquinone; Carbon; Catechol; Chemical sensors; Decoration; Differential pulse voltammetry; Electrical resistivity; Electrochemical analysis; Electrode materials; Engineers; Functional groups; Heterostructures; Hydroquinone; Industrial wastes; Isomers; MOF-derived N-PC; Nitrogen; Polymer matrix composites; Redox reactions; Self-assembly; Ti3C2; Wastewater; Hydroquinone; Catechol; Ti3C2; MOF-derived N-PC; Differential pulse voltammetry
• ISSN: 0925-4005; 1873-3077
• DOI: 10.1016/j.snb.2020.128386

[Display omitted] •Abundant hydroxyl groups on the surface of Ti3C2 after KOH intercalation.•MOF-5-NH2-derived N-PC used as intercalator alleviate stacking problem of Ti3C2.•Alk-Ti3C2/N-PC composite are prepared by a facile self-assembling process.•Very low detection limits are achieved for the simultaneous detection of HQ and CT. The functional groups on the surface of Ti3C2 can be tailored by alkalization treatment to design novel electrode materials. However, the restacking of Ti3C2 greatly hinders its practical application. To address this limitation, a facile self-assembling method was developed to engineer a novel type of heterostructure (Ti3C2/MOF). The structure alk-Ti3C2/N-PC was prepared by combining MOF-5-NH2-derived nitrogen-doped porous carbon (N-PC) with alk-Ti3C2 prepared by the acid etching and alkaline intercalation treatment of Ti3C2. This strategy could effectively prevent Ti3C2 sheets from restacking and enable the sensing of benzenediol through hydrogen-bond interaction, brought about by the abundant OH functional groups on the alk-Ti3C2 and numerous CN bonds on NPC. Because of the advantages of the excellent electrical conductivity of alk-Ti3C2 and the large surface area of NPC, hydroquinone (HQ) and catechol (CT) could be detected on the basis of their benzenediol/benzoquinone redox reactions. Under optimized conditions, a wide linear range of 0.5―150 μM with low detection limits of 4.8 nM (S/N = 3) and 3.1 nM (S/N = 3) for HQ and CT, respectively, were obtained. The alk-Ti3C2/NPC electrochemical sensor was applied to detect HQ and CT in industrial wastewater, and acceptable recoveries were achieved. Hence, the decoration of alk-Ti3C2 with NPC is an innovative method to engineer various alk-Ti3C2-based composites for the detection of phenolic isomers and environmental analyses.