Kinetics of n-propylmercaptan oxidation by cobalt(III) octahydroxyphthalocyanine in an alkali medium

The specific features of the association of cobalt octahydroxyphthalocyanine in aqueous alkaline solutions have been investigated by electron spectroscopy. The kinetic parameters of the oxidation of n -propylmercaptan by the phthalocyanine complex of cobalt in the absence of oxygen have been determi...

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Bibliographic Details
Published inKinetics and catalysis Vol. 57; no. 3; pp. 313 - 318
Main Authors Ziyadova, T. M., Burmistrov, V. A., Maizlish, V. E., Koifman, O. I.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.05.2016
Subjects
Catalysis
Chemistry
Chemistry and Materials Science
Physical Chemistry
propylmercaptan
kinetics
cobalt octahydroxyphthalocyanine
catalytic oxidation
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Summary:The specific features of the association of cobalt octahydroxyphthalocyanine in aqueous alkaline solutions have been investigated by electron spectroscopy. The kinetic parameters of the oxidation of n -propylmercaptan by the phthalocyanine complex of cobalt in the absence of oxygen have been determined. The association leads to a decrease in the activity of the complex and to changes in activation parameters.
ISSN:0023-1584
1608-3210
DOI:10.1134/S0023158416030186