A Novel One-Dimensional Zinc Coordination Polymer, [Zinc{(4,5-ditetrazoyl)-imidazole}{(1,10)-phenanthroline}(H2O)]n

The reaction of 4,5‐dicyanoimidazole with ZnCl2 and NaN3 in the presence of (1,10)‐phenanthroline and water affords a novel one‐dimensional zinc coordination polymer, [zinc{(4,5‐ditetrazoyl)‐imidazole}{(1,10)‐phenanthroline}(H2O)]n (1), in which 1 contains a ditetrazole ligand and strongly supports...

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Published inZeitschrift für anorganische und allgemeine Chemie (1950) Vol. 630; no. 10; pp. 1367 - 1370
Main Authors Zhao, Hong, Ye, Qiong, Wu, Qian, Song, Yu-Mei, Liu, Yu-Juan, Xiong, Ren-Gen
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 01.08.2004
WILEY‐VCH Verlag
Subjects
(4,5‐Ditetrazoyl)‐imidazole
5-Ditetrazoyl)-imidazole
Tetrazole
Zinc
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Summary:The reaction of 4,5‐dicyanoimidazole with ZnCl2 and NaN3 in the presence of (1,10)‐phenanthroline and water affords a novel one‐dimensional zinc coordination polymer, [zinc{(4,5‐ditetrazoyl)‐imidazole}{(1,10)‐phenanthroline}(H2O)]n (1), in which 1 contains a ditetrazole ligand and strongly supports the Demko‐Sharpless' tetrazole synthesis reaction. The structure was determined by single crystal X‐ray diffraction. Crystal data: P21/n; a = 11.908(18); b = 8.133(10); c = 21.01(3) Å; β = 112.46(7)°; V = 1880(1) Å3; Z = 4; R1 = 0.0882, wR2 = 0.2091.
Bibliography:istex:89C5B7F73A4E8F7BD728AAD7C1F8065B9B340C2D
ArticleID:ZAAC200400126
ark:/67375/WNG-8Q9QV997-2
ISSN:0044-2313
1521-3749
DOI:10.1002/zaac.200400126