Stepwise Assembly of Mixed Metal Dinuclear Carbonyl Complexes

The one‐pot/three‐step solution synthesis of a library of nine directional, dinuclear mixed‐metal complexes composed of different metal‐carbonyl units (M = Cr, Mo, W) and a bifunctional bridging isocyanide Schiff‐base ligand is described. The well‐defined metal sequence in these complexes with Cr, M...

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Bibliographic Details
Published inEuropean journal of inorganic chemistry Vol. 2003; no. 21; pp. 3918 - 3923
Main Authors Heinze, Katja, Jacob, Volker
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 01.11.2003
WILEY‐VCH Verlag
Wiley
Subjects
Bridging ligands
Chemistry
Chemistry, Inorganic & Nuclear
Group 6 elements
Heterometallic complexes
Isocyanide ligands
Isomers
Physical Sciences
Science & Technology
heterometallic complexes
POLYMERS
isomers
MULTIBIT INFORMATION-STORAGE
TRIPYRIDYLDIAMIDO DIANION
CHROMIUM
DIMERS
OLIGOMERS
group 6 elements
bridging ligands
RUTHENIUM(II)
7-MEMBERED RING SYSTEMS
CRYSTALS
TPDA(2-)
isocyanide ligands
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Summary:The one‐pot/three‐step solution synthesis of a library of nine directional, dinuclear mixed‐metal complexes composed of different metal‐carbonyl units (M = Cr, Mo, W) and a bifunctional bridging isocyanide Schiff‐base ligand is described. The well‐defined metal sequence in these complexes with Cr, Mo, and W in two positions can be determined post‐synthesis by a combination of spectroscopic methods. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)
Bibliography:istex:A88305E6413C8141DCA104F4FAB58FC397B20317
ArticleID:EJIC200300272
ark:/67375/WNG-54G06KL8-9
ISSN:1434-1948
1099-0682
DOI:10.1002/ejic.200300272