Mechanochemical Synthesis of a Cocrystal of Two Supramolecular Hydrogen-Bonded Aggregates of 1,3,6,8-Tetraazatricyclo[4.3.1.13,8]undecane (TATU) with 4-tert-Butylphenol Bearing Different Hydrogen Bonding Interactions

The synthesis and single crystal structure of a new cocrystal, which is composed of OHphenolic∙∙∙OHphenolic∙∙∙Naminalic supramolecular heterosynthons assembled from 4-tert-butylphenol and the macrocyclic aminal TATU, is presented. This cocrystal was prepared by solvent-free assisted grinding, which...

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Bibliographic Details
Published inCrystals (Basel) Vol. 8; no. 8; p. 309
Main Authors Rivera, Augusto, Rojas, Jicli, Ríos-Motta, Jaime, Bolte, Michael
Format Journal Article
LanguageEnglish
Published Basel MDPI AG 01.08.2018
Subjects
aminal structure
Chemistry
cocrystals
crystal engineering
Crystal structure
Hydrogen bonding
Hydrogen bonds
Nitrogen
noncovalent interactions
Phenols
Single crystals
Software
supramolecular chemistry
Synthesis
United Kingdom > UK
Colombia
Germany
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Summary:The synthesis and single crystal structure of a new cocrystal, which is composed of OHphenolic∙∙∙OHphenolic∙∙∙Naminalic supramolecular heterosynthons assembled from 4-tert-butylphenol and the macrocyclic aminal TATU, is presented. This cocrystal was prepared by solvent-free assisted grinding, which is a commonly used mechanochemical method. Crystal structure, supramolecular assembly through hydrogen bonding interactions as well as the physical and spectroscopic properties of the title cocrystal are presented in this paper.
ISSN:2073-4352
2073-4352
DOI:10.3390/cryst8080309