Ultrafast high-temperature sintering of silicon nitride: A comparison with the state-of-the-art techniques

Ultrafast High-temperature Sintering (UHS) has been successfully applied to fabricate the silicon nitride (Si3N4) bulks, as the first attempt of ultra-rapid consolidation of a non-oxide ceramics. At a heating rate of 875 °C/min, the bulk Si3N4 ceramic with a relative density greater than 96 % and an...

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Published inJournal of the European Ceramic Society Vol. 41; no. 13; pp. 6338 - 6345
Main Authors Luo, Rui-Xin, Kermani, Milad, Guo, Zhao-Liang, Dong, Jian, Hu, Chun-Feng, Zuo, Fei, Grasso, Salvatore, Jiang, Bei-Bei, Nie, Guang-Lin, Yan, Zheng-Qing, Wang, Qiang, Gan, Yan-Ling, He, Fu-Po, Lin, Hua-Tay
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 01.10.2021
Subjects
Online AccessGet full text
ISSN0955-2219
1873-619X
DOI10.1016/j.jeurceramsoc.2021.06.021

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Abstract Ultrafast High-temperature Sintering (UHS) has been successfully applied to fabricate the silicon nitride (Si3N4) bulks, as the first attempt of ultra-rapid consolidation of a non-oxide ceramics. At a heating rate of 875 °C/min, the bulk Si3N4 ceramic with a relative density greater than 96 % and an α-β phase transformation degree above 80 % could be obtained within 300 s. The effects of ultrafast heating on the liquid phase sintering (LPS) were also comparatively studied. Results showed that, the ultrafast heating rate and high temperature under UHS might promote the LPS system evolving to a nonequilibrium state. By comparing with other pressureless sintering processes with much lower heating rates, UHS apart from reducing the processing time, and it is also an effective method to form a bimodal microstructure composed of interlocked rod-like β-Si3N4 grains.
AbstractList Ultrafast High-temperature Sintering (UHS) has been successfully applied to fabricate the silicon nitride (Si3N4) bulks, as the first attempt of ultra-rapid consolidation of a non-oxide ceramics. At a heating rate of 875 °C/min, the bulk Si3N4 ceramic with a relative density greater than 96 % and an α-β phase transformation degree above 80 % could be obtained within 300 s. The effects of ultrafast heating on the liquid phase sintering (LPS) were also comparatively studied. Results showed that, the ultrafast heating rate and high temperature under UHS might promote the LPS system evolving to a nonequilibrium state. By comparing with other pressureless sintering processes with much lower heating rates, UHS apart from reducing the processing time, and it is also an effective method to form a bimodal microstructure composed of interlocked rod-like β-Si3N4 grains.
Author Kermani, Milad
Jiang, Bei-Bei
Dong, Jian
Nie, Guang-Lin
Zuo, Fei
Wang, Qiang
Grasso, Salvatore
Yan, Zheng-Qing
Hu, Chun-Feng
Guo, Zhao-Liang
Gan, Yan-Ling
Lin, Hua-Tay
Luo, Rui-Xin
He, Fu-Po
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  fullname: Luo, Rui-Xin
  organization: School of Electromechanical Engineering, Guangdong University of Technology, Guangzho, 510006, China
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  givenname: Milad
  surname: Kermani
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  organization: Key Laboratory of Advanced Technologies of Materials, Ministry of Education, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu, 610031, China
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  givenname: Zhao-Liang
  surname: Guo
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  surname: Dong
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  organization: Key Laboratory of Advanced Technologies of Materials, Ministry of Education, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu, 610031, China
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  givenname: Chun-Feng
  surname: Hu
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  surname: Zuo
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  email: zuofei@gdut.edu.cn
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  surname: Grasso
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  organization: Key Laboratory of Advanced Technologies of Materials, Ministry of Education, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu, 610031, China
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  surname: Jiang
  fullname: Jiang, Bei-Bei
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  surname: Nie
  fullname: Nie, Guang-Lin
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  givenname: Zheng-Qing
  surname: Yan
  fullname: Yan, Zheng-Qing
  organization: School of Electromechanical Engineering, Guangdong University of Technology, Guangzho, 510006, China
– sequence: 11
  givenname: Qiang
  surname: Wang
  fullname: Wang, Qiang
  organization: School of Electromechanical Engineering, Guangdong University of Technology, Guangzho, 510006, China
– sequence: 12
  givenname: Yan-Ling
  surname: Gan
  fullname: Gan, Yan-Ling
  organization: School of Environmental Sciences and Engineering, Sun Yat-Sen University, Guangzhou, 510275, China
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  givenname: Fu-Po
  surname: He
  fullname: He, Fu-Po
  organization: School of Electromechanical Engineering, Guangdong University of Technology, Guangzho, 510006, China
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  givenname: Hua-Tay
  surname: Lin
  fullname: Lin, Hua-Tay
  email: huataylin@gdut.edu.cn
  organization: School of Electromechanical Engineering, Guangdong University of Technology, Guangzho, 510006, China
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Keywords Phase transformation
Ultrafast high-temperature sintering
Liquid phase sintering
Microstructure
Silicon nitride
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Snippet Ultrafast High-temperature Sintering (UHS) has been successfully applied to fabricate the silicon nitride (Si3N4) bulks, as the first attempt of ultra-rapid...
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SubjectTerms Liquid phase sintering
Microstructure
Phase transformation
Silicon nitride
Ultrafast high-temperature sintering
Title Ultrafast high-temperature sintering of silicon nitride: A comparison with the state-of-the-art techniques
URI https://dx.doi.org/10.1016/j.jeurceramsoc.2021.06.021
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