Ultrafast high-temperature sintering of silicon nitride: A comparison with the state-of-the-art techniques

• Published in: Journal of the European Ceramic Society Vol. 41; no. 13; pp. 6338 - 6345
• Main Authors: Luo, Rui-Xin, Kermani, Milad, Guo, Zhao-Liang, Dong, Jian, Hu, Chun-Feng, Zuo, Fei, Grasso, Salvatore, Jiang, Bei-Bei, Nie, Guang-Lin, Yan, Zheng-Qing, Wang, Qiang, Gan, Yan-Ling, He, Fu-Po, Lin, Hua-Tay
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.10.2021
• Subjects: Liquid phase sintering; Microstructure; Phase transformation; Silicon nitride; Ultrafast high-temperature sintering; Phase transformation; Ultrafast high-temperature sintering; Liquid phase sintering; Microstructure; Silicon nitride
• ISSN: 0955-2219; 1873-619X
• DOI: 10.1016/j.jeurceramsoc.2021.06.021

Ultrafast High-temperature Sintering (UHS) has been successfully applied to fabricate the silicon nitride (Si3N4) bulks, as the first attempt of ultra-rapid consolidation of a non-oxide ceramics. At a heating rate of 875 °C/min, the bulk Si3N4 ceramic with a relative density greater than 96 % and an α-β phase transformation degree above 80 % could be obtained within 300 s. The effects of ultrafast heating on the liquid phase sintering (LPS) were also comparatively studied. Results showed that, the ultrafast heating rate and high temperature under UHS might promote the LPS system evolving to a nonequilibrium state. By comparing with other pressureless sintering processes with much lower heating rates, UHS apart from reducing the processing time, and it is also an effective method to form a bimodal microstructure composed of interlocked rod-like β-Si3N4 grains.