Polyvinylidene fluoride-based novel polymer electrolytes for magnesium-rechargeable batteries with Mg(CF3SO3)2

Magnesium trifluoromethanesulfonate (Mg (CF3SO3)2)‐based polymer electrolytes (PEs) have been prepared with polyvinylidene fluoride (PVdF) as a host matrix. Tetraglyme and tetrabutyl ammonium chloride (TBACl) were used as plasticizer and filler, respectively, in the matrix by solution‐casting techni...

Full description

Saved in:
Bibliographic Details
Published inJournal of applied polymer science Vol. 112; no. 5; pp. 3024 - 3029
Main Authors Aravindan, Vanchiappan, Karthikaselvi, G., Vickraman, P., Naganandhini, S. P.
Format Journal Article
LanguageEnglish
Published Hoboken Wiley Subscription Services, Inc., A Wiley Company 05.06.2009
Wiley
Subjects
Applied sciences
Blends
Direct energy conversion and energy accumulation
Electrical engineering. Electrical power engineering
Electrical power engineering
Electrochemical conversion: primary and secondary batteries, fuel cells
Exact sciences and technology
Forms of application and semi-finished materials
Polymer industry, paints, wood
Technology of polymers
tetraglyme
TBACl
Electrical properties
magnesium triflate
Ionic conductivity
Polymer solid electrolyte
Secondary cell
Experimental study
PVdF
Property formulation relationship
Quaternary ammonium compound
Additive
Electrochemical properties
Plasticizer
cyclic voltammetry
Morphology
Vinylidene fluoride polymer
magnesium batteries
Battery
Activation energy
Magnesium Compounds
Online AccessGet full text

Cover

More Information
Summary:Magnesium trifluoromethanesulfonate (Mg (CF3SO3)2)‐based polymer electrolytes (PEs) have been prepared with polyvinylidene fluoride (PVdF) as a host matrix. Tetraglyme and tetrabutyl ammonium chloride (TBACl) were used as plasticizer and filler, respectively, in the matrix by solution‐casting technique. The electrolyte containing 5 wt % TBACl exhibits the conductivity of 0.442 mS cm−1 at ambient temperature. X‐ray diffraction study reveals the amorphous nature of the PE. Linear sweep voltammetry was also performed to evaluate the decomposition potential of the electrolyte. The morphological features were analyzed by scanning electron microscope. The activation energy has also been calculated, which corroborates the ionic conductivity results. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009
Bibliography:istex:3D3FDF0D2A478B4B275181BBDE95A8A639E5F82B
ark:/67375/WNG-66LR5832-L
ArticleID:APP29877
ObjectType-Article-2
SourceType-Scholarly Journals-1
ObjectType-Feature-1
content type line 23
ISSN:0021-8995
1097-4628
DOI:10.1002/app.29877