Novel Multicomponent Powders from the AlCrFeMnMo Family Synthesized by Mechanical Alloying

• Published in: Advanced engineering materials Vol. 21; no. 12
• Main Authors: Stasiak, Tomasz, Kumaran, Surya Nilamegam, Touzin, Matthieu, Béclin, Franck, Cordier, Catherine
• Format: Journal Article
• Language: English
• Published: Wiley 01.12.2019
• Series: Advanced Engineering Materials
• Subjects: Chemical Sciences; Condensed Matter; high-entropy alloys; Material chemistry; Materials Science; mechanical alloying; metallurgy; multicomponent alloys; Physics; powder technologies
• ISSN: 1438-1656; 1527-2648
• DOI: 10.1002/adem.201900808

High‐entropy alloys (HEAs) and multicomponent alloys are known for their promising properties and the almost infinite possibilities of the design of new compositions. The Al–Cr–Fe–Mn–Mo family of HEAs is chosen to promote the formation of a body‐centered cubic (bcc) structure that exhibits high hardness and yield strength. Powder metallurgy is preferred to the liquid route to avoid segregation problems. Two compositions of alloyed powder, equiatomic and optimized, are successfully prepared by mechanical alloying. X‐ray diffraction (XRD) indicates the formation of two major bcc phases: bcc#1 (a1 = 3.13–3.14 Å) and bcc#2 (a2 = 2.87–2.94 Å). Energy transferred during milling depends greatly on the milling device and process conditions. Scanning electron microscopy–energy‐dispersive X‐ray spectroscopy (SEM–EDX) images reveal that high‐energy shocks of balls enable to elaborate homogeneous powder with controlled Fe contamination coming from the grinding vial and balls, whereas low‐energy shocks enable to produce powder free of contamination by Fe, with heterogeneous particles. Finally, the milling process is optimized to obtain a homogeneous alloyed powder with as little contamination as possible. Mechanical alloying (MA) enables to produce the alloyed high‐entropy and multicomponent powders. Two compositions from the novel multicomponent alloy family AlCrFeMnMo are prepared via the MA method. Alloys present a sufficient chemical homogeneity and two‐phase, nanocrystalline body‐centered cubic (bcc) structure. The homogeneity of the powder depends greatly on a milling device.