DESIGN AND SYNTHESIS OF ARTIFICIAL SIDEROPHORES - LYSINE-BASED TRISCATECHOLATE LIGANDS AS A MODEL FOR ENTEROBACTIN

An enantiomeric pair of triscatecholate ligands have been prepared as a model for siderophore enterobactin, using protected derivatives of L- or D-lysine, 1,2-diaminoethane and 2,3-dihydroxybenzoic acid. The ligands have greater chemical stability and higher water solubility than enterobactin, and f...

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Bibliographic Details
Published inChemistry letters no. 9; pp. 849 - 850
Main Authors AKIYAMA, M, IKEDA, T
Format Journal Article
LanguageEnglish
Published TOKYO Chemical Soc Japan 01.09.1995
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
IRON
ENTEROCHELIN
ANALOGS
ESCHERICHIA-COLI
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Summary:An enantiomeric pair of triscatecholate ligands have been prepared as a model for siderophore enterobactin, using protected derivatives of L- or D-lysine, 1,2-diaminoethane and 2,3-dihydroxybenzoic acid. The ligands have greater chemical stability and higher water solubility than enterobactin, and form chiral complexes with iron(III), as enterobactin does.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.1995.849