Reactive phenylbenzimidazole UV absorbers and their application to cellulose textiles

• Published in: Journal of applied polymer science Vol. 112; no. 6; pp. 3605 - 3612
• Main Authors: Kubáč, Lubomír, Akrman, Jiří, Burgert, Ladislav, Dvorský, Drahomír, Grüner, Pavel
• Format: Journal Article
• Language: English
• Published: Hoboken Wiley Subscription Services, Inc., A Wiley Company 15.06.2009; Wiley
• Subjects: Applied sciences; cellulose; Compounding ingredients; cotton; Exact sciences and technology; Fibers and threads; Forms of application and semi-finished materials; phenylbenzimidazoles; Polymer industry, paints, wood; Stabilizers (antioxydants, antiozonants, etc.); sun protection; Technology of polymers; UV absorbers; Substituent effect; Plant fiber; Cotton; Experimental study; Property processing relationship; sun protection; Dyeing; UV absorbers; Additive; Ultraviolet resistance; Stabilizer agent; Benzimidazole derivatives; Chemical treatment; cellulose; Natural fiber; Triazine derivatives; Chemical properties; Woven material; Ultraviolet absorbent; phenylbe; nzimidazoles
• ISSN: 0021-8995; 1097-4628
• DOI: 10.1002/app.29739

New types of reactive UV absorbers for applications to cellulose textiles have been prepared. These substances are condensation products of sulfobenzimidazolaniline, cyanuric chloride, and aminophenyl-(2-sulfethoxy)-sulfone. They were applied to bleached, unbleached, as well as dyed cellulose textiles with the aim to increase the protection effect of these textiles against UV radiation. All the tested textiles showed a marked increase in the UV protection factor (UPF). The effects of the UV absorbers tested neither interfere with the function of fluorescent brighteners (FBs) nor affect the hue of the used dyestuffs. They exhibit synergistic effect in the protection effectiveness against UV radiation: the UV absorbers used together with dyestuffs and FBs have a higher UPF factor than is the sum of UPF contributions of the individual components.