An Organic–Inorganic Hybrid Polymer Based on Molybdenum(V) Phosphate and Cadmium(II) Complex
An unusual organic–inorganic hybrid polymer, [Cd(pztt)(H 2 O) 2 ] 4 [CdMo 12 V O 24 (OH) 6 (HPO 4 ) 4 (H 2 PO 4 ) 2 (PO 4 ) 2 ]·10H 2 O (pztt = 3-(pyrazin-2-yl)-5-(1H-1,2,4-triazol-3-yl)-1,2,4-triazliyi) ( 1 ), have been hydrothermally synthesized and structurally characterized by the elemental anal...
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Published in | Journal of inorganic and organometallic polymers and materials Vol. 24; no. 4; pp. 759 - 765 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
Boston
Springer US
01.07.2014
|
Subjects | |
Online Access | Get full text |
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Summary: | An unusual organic–inorganic hybrid polymer, [Cd(pztt)(H
2
O)
2
]
4
[CdMo
12
V
O
24
(OH)
6
(HPO
4
)
4
(H
2
PO
4
)
2
(PO
4
)
2
]·10H
2
O (pztt = 3-(pyrazin-2-yl)-5-(1H-1,2,4-triazol-3-yl)-1,2,4-triazliyi) (
1
), have been hydrothermally synthesized and structurally characterized by the elemental analysis, TG, IR, UV–Vis, PXRD and the single-crystal X-ray diffraction. In compound
1
, the sandwich-type {Cd[Mo
6
P
4
O
31
]
2
} units are modified with Cd(pztt)(H
2
O)
2
fragments to lead bi-supported dimer clusters, which are further linked by binuclear complex subunits [Cd
2
(pztt)
2
(H
2
O)
4
] to yield unusual 1-D chains. The 1-D chains are further packed into 2-D and 3-D supramolecular assemblies via strong hydrogen-bonding interactions. In addition, the electrochemical behavior of
1
-CPE and the photoluminescence properties of
1
in the solid state at room temperature have been investigated in detail. |
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Bibliography: | ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23 |
ISSN: | 1574-1443 1574-1451 |
DOI: | 10.1007/s10904-014-0029-9 |