A comparative study of compressed lateritic earth bricks stabilized with natural pozzolan-based geopolymer binders synthesized in acidic and alkaline conditions

• Published in: Construction & building materials Vol. 400; p. 132652
• Main Authors: Aurelie Tchouateu Kamwa, Rolande, Tchadjie Noumbissie, Leonel, Tome, Sylvain, Idriss, Eguekeng, Giogetti Deutou Nemaleu, Juvenal, Tommes, Birgit, Woschko, Dennis, Janiak, Christoph, Etoh, Marie-Annie
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 12.10.2023
• Subjects: Acidic activator; Alkaline activators; Compressed earth brick; Geopolymer binder; Lateritic soil; Natural pozzolan; Acidic activator; Geopolymer binder; Compressed earth brick; Lateritic soil; Natural pozzolan; Alkaline activators
• ISSN: 0950-0618; 1879-0526
• DOI: 10.1016/j.conbuildmat.2023.132652

•Natural pozzolan reacts better in acidic activation than in alkaline activation.•Acidic-activated geopolymer binder exhibited more ability in the production of laterite-based compressed earth bricks.•The formation open voids formation is responsible for the lowering of the recorded strength development.•The carbonation reaction between the free Na+ and the CO2 favoured the presence of efflorescence endangering the strength of this alkali-stabilized CEBs. Two geopolymer binder systems made under alkaline and acidic conditions have been evaluated for the stabilization of compressed lateritic earth bricks (CEBs) using natural pozzolan as aluminosilicate precursor. The preparation of alkaline and acidic activators involved the combination of sodium silicate and 10 mol/L sodium hydroxide solutions, as well as 10 mol/L phosphoric acid solutions, respectively. CEBs were prepared to comprise different proportions of natural pozzolan of 5, 10, 15, and 20 %. The physico-mechanical and mineralogical properties of compressed earth bricks were studied using the compressive strength, the dry and wet bulk density, the water absorption rate, Fourier transform infrared spectroscopy (FTIR), powder X-Ray Diffraction (PXRD) and optical microscopy (OM).The results showed that in the acid environment, the mechanical performance increased considerably with the pozzolan content and slightly with the curing time, whereas in the alkaline environment these performance decrease for the sample with 0 to 10 % of pozzolan and remain constant for the sample with 15 to 20 % of pozzolan after 14 days of curing. The utilization of acid-activated geopolymer binder in the production of laterite-based compressed earth bricks has been shown to be more effective compared to the utilization of an alkali-activated geopolymer binder. The high performance of acid-stabilized CEBs is related to the best reactivity of natural pozzolan in acid medium allowing the formation of Al-O-P bonds.