Photochemical preparation of aluminium oxide layers via vacuum ultraviolet irradiation of a polymeric hexanoato aluminium complex

• Published in: Materials chemistry and physics Vol. 137; no. 3; pp. 1046 - 1052
• Main Authors: Wennrich, L., Khalil, H., Bundesmann, C., Decker, U., Gerlach, J.W., Helmstedt, U., Manova, D., Naumov, S., Prager, L.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 15.01.2013
• Subjects: Amorphous materials; Monolayers; Organometallic compounds; Oxides; Thin films; Thin films; Oxides; Amorphous materials; Organometallic compounds; Monolayers
• ISSN: 0254-0584; 1879-3312
• DOI: 10.1016/j.matchemphys.2012.11.026

By means of photochemical conversion of thin layers of a polymeric hexanoato aluminium complex as the precursor, thin aluminium oxide layers were prepared onto silicon wafers. The precursor compound was synthesized and characterized by several analytical techniques like NMR, FTIR, XPS, ICP, and found to be a polymeric aluminium-containing coordination compound which has been proposed to be a hydroxo-bridged aluminium chain with pendant hexanoyl side-chains ascertained as catena-poly[{di(κ-O,O-hexanoato)aluminium}(μ-hydroxo)] (PHAH). Thin layers deposited from a solution of PHAH in toluene onto silicon wafers were irradiated using VUV radiation from a xenon excimer lamp. The layers were characterized by XPS, XRD, XRR, and spectroscopic ellipsometry. VUV radiation with a radiant exposure of E = 36 J cm−2 led to almost carbon-free amorphous layers with a composition close to that of alumina having a density of about 2.1 g cm−3. Thus, using the example of a polymeric aluminium complex, the potential of the photochemical conversion of metal complexes into oxides could be shown as an alternative method, in addition to sol–gel techniques, for the generation of thin plane metal-oxide layers at normal temperature and pressure. [Display omitted] ► A polymeric aluminium complex was synthesized and characterized by NMR, FTIR, XPS and ICP. ► Thin layers of the compound were irradiated using vacuum-UV radiation and converted to AlOx. ► Quantum-chemical calculations explain the conversion mechanism.