Individual extraction constants of some univalent cations in the two-phase water–phenyltrifluoromethyl sulfone system

From extraction experiments and γ-activity measurements, the exchange extraction constants corresponding to the general equilibrium M + (aq) + Cs + (org) ⟺ M + (org) + Cs + (aq) taking place in the two-phase water–phenyltrifluoromethyl sulfone (abbrev. FS 13) system (M +  = Li + , H 3 O + , Na + , ,...

Full description

Saved in:
Bibliographic Details
Published inJournal of radioanalytical and nuclear chemistry Vol. 288; no. 1; pp. 177 - 180
Main Authors Makrlik, E, Vanura, P, Selucky, P
Format Journal Article
LanguageEnglish
Published Dordrecht Springer Netherlands 01.04.2011
Subjects
Cations
Chemistry
Chemistry and Materials Science
Constants
Diagnostic Radiology
Extraction
Hadrons
Heavy Ions
Inorganic Chemistry
Mathematical analysis
Nuclear Chemistry
Nuclear Physics
Physical Chemistry
Sulfones
Extraction constants
Water–phenyltrifluoromethyl sulfone system
Univalent cations
Online AccessGet full text

Cover

More Information
Summary:From extraction experiments and γ-activity measurements, the exchange extraction constants corresponding to the general equilibrium M + (aq) + Cs + (org) ⟺ M + (org) + Cs + (aq) taking place in the two-phase water–phenyltrifluoromethyl sulfone (abbrev. FS 13) system (M +  = Li + , H 3 O + , Na + , , Ag + , Tl + , K + , Rb + ; aq = aqueous phase, org = FS 13 phase) were evaluated. Furthermore, the individual extraction constants of the M + cations in the mentioned two-phase system were calculated; they were found to increase in the series of Li + < H 3 O + < Na + < < Ag + < Tl + < K + < Rb + < Cs + .
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0236-5731
1588-2780
DOI:10.1007/s10967-010-0893-x