A giant metallo-supramolecular cage encapsulating a single-molecule magnet

A giant metallo-supramolecular cage encapsulating a single-molecule magnet, [Ag42{Ho(W5O18)2}(t-BuC≡C)28Cl4]OH, is prepared and structurally characterized. It shows an interesting "peanut-like" structure and remains intact in solution as demonstrated by NMR studies.

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 49; no. 35; pp. 3658 - 3660
Main Authors Li, Yu-Yang, Gao, Feng, Beves, Jonathon E, Li, Yi-Zhi, Zuo, Jing-Lin
Format Journal Article
LanguageEnglish
Published England 07.05.2013
Subjects
Cage
Encapsulating
Nuclear magnetic resonance
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Summary:A giant metallo-supramolecular cage encapsulating a single-molecule magnet, [Ag42{Ho(W5O18)2}(t-BuC≡C)28Cl4]OH, is prepared and structurally characterized. It shows an interesting "peanut-like" structure and remains intact in solution as demonstrated by NMR studies.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc41237g